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A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles

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Abstract

Redox-active ligands are of interest for their ability to link metal centres and generate electroactive materials. We report the synthesis of 9-hydrogen-2,3,7-trihydroxyfluorone, which is able to serve as a bridging ligand and has the potential to exist in multiple oxidation states. Anionic [4+4] metallocycles in which Mo or W centres are linked by the trianion of this ligand are also described.

Graphical abstract: A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles

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Article information


Submitted
12 May 2020
Accepted
24 Jun 2020
First published
29 Jun 2020

New J. Chem., 2020, Advance Article
Article type
Letter

A new fluorone-based bridging ligand for discrete and polymeric assemblies including Mo and W based [4+4] metallocycles

A. L. Sutton, B. F. Abrahams, T. A. Hudson and R. Robson, New J. Chem., 2020, Advance Article , DOI: 10.1039/D0NJ02413A

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