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A new family of silver(I) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

Abstract

The reactions of the phosphanylborane Ph2PBH2·NMe3 (L) with Ag[FAl{OC6F10(C6F5)}3] (Ag[FAl]) and AgBF4 are studied. The first reaction allowed for the synthesis of the coordination compounds [Ag(Ph2P-BH2·NMe3)(CH3CN)][FAl] (1), [Ag(Ph2P-BH2·NMe3)2][FAl] (2) and [Ag(Ph2P-BH2·NMe3)3][FAl] (3), while the second reaction afforded the one-dimentional coordination polymer [Ag(Ph2P-BH2·NMe3)]n[BF4]n (4). Compounds 1-4 are the first reported Ag(I) complexes stabilised by phosphanylboranes.

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Supplementary files

Article information


Submitted
03 Apr 2020
Accepted
04 May 2020
First published
04 May 2020

New J. Chem., 2020, Accepted Manuscript
Article type
Letter

A new family of silver(I) complexes stabilised by the phosphanylborane (C6H5)2PBH2·N(CH3)3

M. Moussa, C. Marquardt, O. Hegen, M. Seidl and M. Scheer, New J. Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0NJ01679A

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