Synthesis and characterization of nitrogen-based ionic liquids bearing allyl group and examples of their application
The syntheses and full spectral (NMR, MS, IR), thermal (DSC) and ion chromatographic characterization of two series of amine-derived ionic liquids bearing allyl substituent and having chloride or bis(trifluoromethanesulfonyl)amide anion have been presented. The analysis of dependence 1H NMR chemical shift values of selected protons on the cation and anion structure has been conducted. DSC analysis records together with ion chromatography analysis results have been presented and interpreted. Moreover, a selection of obtained chloride ionic liquids have been transformed into corresponding chlorocobaltates and chlorozincates or used as a substrate in thiol-ene click reaction to indicate their potential as precursors of catalysts or various surfaces modifiers.