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Yb3+/Er3+ co-doped Dion–Jacobson niobium layered perovskites as NIR-to-green upconversion materials

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Abstract

Here, the upconversion behaviour of Yb3+/Er3+-codoped layered Dion–Jacobson calcium-niobium perovskites was investigated. This lanthanide pair is majorly responsible for the efficient green and red anti-Stokes-like emissions in rare-earth fluorides. Layered perovskites of the composition KCa2Nb3O10 were synthesized by the ceramic method by replacing 1% per mol of Ca2+ by lanthanide ions in such a way that the Yb3+:Er3+ molar proportion varied from 2 : 1 to 20 : 1. Non-doped and four doped materials were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), and emission spectroscopy. All materials showed similar XRD profiles, which indicated the isolation of well crystalline single phases. On the other hand, the morphologies accessed by SEM were different: microparticles with well-defined edges were replaced by particles with poorly defined edges, rounded features, and intergrowth aspect when the niobate was doped. The Raman spectra showed modifications in the bands below 200 cm−1 attributed to low-phonon-energy transitions. The doped layered niobates presented almost pure-green emission (excitation at 980 nm), which could be related to the low energy values of the vibrational levels, precluding energy loss. Additionally, the results indicated that the defects generated by the lanthanide ion isomorphic-aliovalent substitution in Ca2+ sites were mainly in the interlayer region. This coupled behaviour reduced the non-radiative decays of the upconversion centres, leading to the formation of an efficient emitting material. The spectroscopic emission data showed a two-photon major mechanism to excite the emitting levels via an energy transfer upconversion (ETU) population process. The lifetime results indicated that increasing the Yb3+ concentration did not lead to non-radiative decay paths. The high efficiency and the versatility of the layered niobate hosts can provide new insights into the design of efficient morphology-controlled materials.

Graphical abstract: Yb3+/Er3+ co-doped Dion–Jacobson niobium layered perovskites as NIR-to-green upconversion materials

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Article information


Submitted
15 Jan 2020
Accepted
30 Mar 2020
First published
31 Mar 2020

New J. Chem., 2020, Advance Article
Article type
Paper

Yb3+/Er3+ co-doped Dion–Jacobson niobium layered perovskites as NIR-to-green upconversion materials

V. Vendruscolo, L. Giordano, V. R. L. Constantino and L. C. V. Rodrigues, New J. Chem., 2020, Advance Article , DOI: 10.1039/D0NJ00261E

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