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Synthesis of amino phosphinodiselenoic acid ester and β-amino diselenides employing P2Se5

Abstract

Synthesis of a new class of amino phosphinodiselenoic acid ester and β-amino diselenides is described by employing a reaction between Nβ-protected amino alkyl iodide and phosphorus pentaselenide (P2Se5). In the assistance of protic solvents amino phosphinodiselenoic acid esters were found to be the major product, whereas β-amino diselenides were formed exclusively when reaction was carried out in polar aprotic solvents.

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Article information


Submitted
02 Jan 2020
Accepted
17 Mar 2020
First published
25 Mar 2020

New J. Chem., 2020, Accepted Manuscript
Article type
Letter

Synthesis of amino phosphinodiselenoic acid ester and β-amino diselenides employing P2Se5

R. Kumar, S. N. Ramachandra, S. G. D.V.R., C. Madhu and V. V. Sureshbabu, New J. Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0NJ00012D

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