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Issue 14, 2020
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Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain

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Abstract

The design and synthesis of several types of metal–organic frameworks (MOFs) have been extensively reported in literature. However, the construction of MOFs using a polymer ligand (polyMOF) is still an emerging field of research. This work reports a new molecular synthetic design strategy to produce a polyMOF composed of polymer ligands with a benzenedicarboxylic acid moiety in the side chain. Powder X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy techniques were used to confirm the structures of the resulting polyMOF. Despite the film shape obtained, the resulting Zn-polyMOF showed crystalline structures, per the microscopy images obtained during powder X-ray diffraction.

Graphical abstract: Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain

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Supplementary files

Article information


Submitted
26 Dec 2019
Accepted
03 Mar 2020
First published
03 Mar 2020

New J. Chem., 2020,44, 5182-5185
Article type
Letter

Construction of a polyMOF using a polymer ligand bearing the benzenedicarboxylic acid moiety in the side chain

K. Yazaki, M. Takahashi, N. Miyajima and M. Obata, New J. Chem., 2020, 44, 5182
DOI: 10.1039/C9NJ06394C

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