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Issue 8, 2020
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Pentasulfurated benzene-cored asterisks: relationship between crystal structure and luminescence properties

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Abstract

Room temperature phosphorescence by metal-free chromophores is quite a rare phenomenon. Hexasulfurated benzene-cored molecules with phenyl substituents, hereafter named asterisks, display bright green phosphorescence in the solid state at room temperature, while they are not luminescent in solution, because of fast non-radiative decay of the lowest excited state. Some of these asterisks are also among the most phosphorescent compounds. Following a search for structure–property relationships, we report here the synthesis, characterization, crystal structure and optical properties of three pentasulfurated benzene-cored asterisks, carrying at the sixth position of the benzene core a cyano (A5CN), a carboxaldehyde (A5CHO), or a vinyl group (A5CC). The most luminescent compound is A5CN, displaying an intense orange phosphorescence in the solid state. Our actual aim is to try and correlate the optical properties with the crystal structure in this series of compounds.

Graphical abstract: Pentasulfurated benzene-cored asterisks: relationship between crystal structure and luminescence properties

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Article information


Submitted
27 Nov 2019
Accepted
23 Jan 2020
First published
23 Jan 2020

New J. Chem., 2020,44, 3249-3254
Article type
Paper

Pentasulfurated benzene-cored asterisks: relationship between crystal structure and luminescence properties

M. Villa, S. D’Agostino, P. Sabatino, R. Noel, J. Busto, M. Roy, M. Gingras and P. Ceroni, New J. Chem., 2020, 44, 3249
DOI: 10.1039/C9NJ05905A

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