Alkali-earth metal lead(II) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4]8+ species

Zhuang Li; Xingxing Jiang; Wenhao Xing; Zheshuai Lin; Jiyong Yao; Yicheng Wu

doi:10.1039/C9NJ05419G

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Alkali-earth metal lead(ii) oxyhalide Ba₂₇Pb₈O₈Cl₅₄ exhibiting interesting [Pb₄Ba₄O₄]⁸⁺ species†

Zhuang Li,^abc Xingxing Jiang,^ac Wenhao Xing,^abc Zheshuai Lin,^ab Jiyong Yao

*^ab and Yicheng Wu^ad

Author affiliations

* Corresponding authors

^a Beijing Center for Crystal Research and Development, Key Lab of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: jyao@mail.ipc.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^c University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^d Institute of Functional Crystal Materials, Tianjin University of Technology, Tianjin 300384, P. R. China

Abstract

The discovery of compounds with novel topologies is likely to extend structural diversity and trigger intriguing physical properties. Herein, the interesting [Pb₄Ba₄O₄]⁸⁺ species has been discovered in alkali-earth metal lead(II) oxyhalide Ba₂₇Pb₈O₈Cl₅₄. Besides, the crystal structures, infrared/Raman spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and electronic band structures of Ba₂₇Pb₈O₈Cl₅₄ have been studied.

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Article information

DOI: https://doi.org/10.1039/C9NJ05419G
Article type: Letter
Submitted: 30 Oct 2019
Accepted: 23 Dec 2019
First published: 26 Dec 2019

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New J. Chem., 2020,44, 1699-1702

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Alkali-earth metal lead(II) oxyhalide Ba₂₇Pb₈O₈Cl₅₄ exhibiting interesting [Pb₄Ba₄O₄]⁸⁺ species

Z. Li, X. Jiang, W. Xing, Z. Lin, J. Yao and Y. Wu, New J. Chem., 2020, 44, 1699 DOI: 10.1039/C9NJ05419G

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