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Alkali-earth metal lead(ii) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4]8+ species

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Abstract

The discovery of compounds with novel topologies is likely to extend structural diversity and trigger intriguing physical properties. Herein, the interesting [Pb4Ba4O4]8+ species has been discovered in alkali-earth metal lead(II) oxyhalide Ba27Pb8O8Cl54. Besides, the crystal structures, infrared/Raman spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and electronic band structures of Ba27Pb8O8Cl54 have been studied.

Graphical abstract: Alkali-earth metal lead(ii) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4]8+ species

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Article information


Submitted
30 Oct 2019
Accepted
23 Dec 2019
First published
26 Dec 2019

New J. Chem., 2020, Advance Article
Article type
Letter

Alkali-earth metal lead(II) oxyhalide Ba27Pb8O8Cl54 exhibiting interesting [Pb4Ba4O4]8+ species

Z. Li, X. Jiang, W. Xing, Z. Lin, J. Yao and Y. Wu, New J. Chem., 2020, Advance Article , DOI: 10.1039/C9NJ05419G

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