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Issue 7, 2020
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Formation of the non-classical interhalide anion [I2Cl] in methyl-bambus[6]uril cavity

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Abstract

Methyl-bambus[6]uril may form a variety of inclusion compounds, especially with anionic species. This communication reports the formation of the non-classical [I2Cl] interhalide ion when chloride-bearing methyl-bambus[6]uril interacts with iodine, both in solution and in the solid state.

Graphical abstract: Formation of the non-classical interhalide anion [I2Cl]− in methyl-bambus[6]uril cavity

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Article information


Submitted
25 Oct 2019
Accepted
30 Jan 2020
First published
30 Jan 2020

New J. Chem., 2020,44, 2697-2700
Article type
Letter

Formation of the non-classical interhalide anion [I2Cl] in methyl-bambus[6]uril cavity

R. S. Cicolani, A. G. S. de Oliveira-Filho, A. P. de L. Batista and G. J. Demets, New J. Chem., 2020, 44, 2697
DOI: 10.1039/C9NJ05352B

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