Issue 1, 2020

An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

Abstract

Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl2 with Ag[C5(CN)4(NH2)] and recrystallization in MeOH, performed in sunlight. The radical was characterized by X-ray diffraction, EPR and UV Vis spectroscopy as well as by cyclovoltammetry and DFT calculations.

Graphical abstract: An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

Supplementary files

Article information

Article type
Paper
Submitted
22 Aug 2019
Accepted
16 Nov 2019
First published
18 Nov 2019

New J. Chem., 2020,44, 72-78

An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

P. R. Nimax, F. Zoller, T. Blockhaus, T. Küblböck, D. Fattakhova-Rohlfing and K. Sünkel, New J. Chem., 2020, 44, 72 DOI: 10.1039/C9NJ04354C

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