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Multinary Copper-based Chalcogenide Nanocrystal Systems from the Perspective of Device Applications

Abstract

Multinary chalcogenide semiconductor nanocrystals are a unique class of materials as they offer flexibility in composition, structure, and morphology for controlled band gap and optical properties. They offer a vast selection of materials for energy conversion, storage, and harvesting applications. Among the multinary chalcogenides, Cu-based compounds are most attractive in terms of sustainability as many of them consist of earth-abundant elements. There has been immense progress in the field of Cu-based chalcogenides for device applications in the recent years. This paper reviews the state of the art synthetic strategies and application of multinary Cu-chalcogenide nanocrystals in photovoltaics, photocatalysis, light emitting diodes, supercapacitors, and luminescent solar concentrators. This includes the synthesis of ternary, quaternary, and quinary Cu-chalcogenide nanocrystals. The review also highlights some emerging experimental and computational characterization approaches for the multinary Cu-chalcogenide semiconductor nanocrystals. It discusses the use of different multinary Cu-chalcogenide compounds, achievements in device performance, and the recent progresses made with multinary Cu-chalcogenide nanocrystals in various energy conversion and energy storage devices. The review concludes with an outlook on some emerging and future device applications for multinary Cu-chalcogenides, such as scalable luminescent solar concentrators and wearable biomedical electronics.

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Article information


Submitted
18 May 2020
Accepted
18 Jun 2020
First published
19 Jun 2020

This article is Open Access

Nanoscale Adv., 2020, Accepted Manuscript
Article type
Minireview

Multinary Copper-based Chalcogenide Nanocrystal Systems from the Perspective of Device Applications

S. Palchoudhury, K. Ramasamy and A. Gupta, Nanoscale Adv., 2020, Accepted Manuscript , DOI: 10.1039/D0NA00399A

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