Process-level modelling and optimization to evaluate metal–organic frameworks for post-combustion capture of CO2

Abstract

Many metal–organic framework (MOF) materials have been reported in the literature as promising for carbon capture applications based on isotherm data or simple adsorbent metrics. However, adsorption process conditions are often neglected in these evaluations. In this study, we performed process-level simulation and optimization of pressure swing adsorption processes on a set of promising MOFs reported in the literature for post-combustion carbon capture. Zeolite 13X was also included as a benchmark material. We examined the ability of the MOFs to achieve the Department of Energy goals of 90% CO₂ purity and 90% CO₂ recovery by employing process-level optimization using three different cycle configurations: a modified Skarstrom cycle, a five-step cycle, and a fractionated vacuum swing adsorption cycle. Then, we ranked the MOFs based on their economic performance by looking at the productivity and energy requirements for each cycle. We compared this ranking of the MOFs with the rankings provided by other metrics and found that the adsorbent rankings suggested by simplified metrics may differ significantly from the rankings predicted by detailed process optimization. The economic optimization analysis suggests that the best performing MOFs from those analyzed here are UTSA-16, Cu-TDPAT, Zn-MOF-74, Ti-MIL-91, and SIFSIX-3-Ni. Looking at the connection between process performance and material properties, we found that high CO₂ working capacity, small pore size, and large difference between the heat of adsorption of CO₂ and N₂ promote CO₂ capture ability based on this small data set. We synthesized one of the top performing MOFs, SIFSIX-3-Ni, and measured its CO₂ and N₂ adsorption isotherms. The measured isotherms allowed us to estimate the N₂ heat of adsorption for SIFSIX-3-Ni, which was not previously available and was required for the process-level modelling.