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Issue 21, 2020
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Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

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Abstract

The first Rh(I)-catalyzed regioselective arylcarboxylation of electron-deficient acrylamides with arylboronic acids under atmospheric pressure of CO2 has been developed. A range of acrylamides and arylboronic acids were compatible with this reaction under redox-neutral conditions, leading to a series of malonate derivatives that are versatile building blocks in organic syntheses.

Graphical abstract: Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

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Article information


Submitted
03 Aug 2020
Accepted
24 Sep 2020
First published
24 Sep 2020

Green Chem., 2020,22, 7328-7332
Article type
Communication

Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

L. Cai, L. Fu, C. Zhou, Y. Gao, S. Li and G. Li, Green Chem., 2020, 22, 7328
DOI: 10.1039/D0GC02667K

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