Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO2

Lei Cai; Lei Fu; Chunlin Zhou; Yuzhen Gao; Shangda Li; Gang Li

doi:10.1039/D0GC02667K

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Rh(i)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO₂†

Lei Cai,^ab Lei Fu,^a Chunlin Zhou,^ab Yuzhen Gao,

^a Shangda Li^a and Gang Li

*^ab

Author affiliations

* Corresponding authors

^a Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, China

^b Fujian College, University of Chinese Academy of Sciences, Beijing, China
E-mail: gangli@fjirsm.ac.cn

Abstract

The first Rh(I)-catalyzed regioselective arylcarboxylation of electron-deficient acrylamides with arylboronic acids under atmospheric pressure of CO₂ has been developed. A range of acrylamides and arylboronic acids were compatible with this reaction under redox-neutral conditions, leading to a series of malonate derivatives that are versatile building blocks in organic syntheses.

This article is part of the themed collections: CO2 Utilisation and 2020 Green Chemistry Hot Articles

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Supplementary files

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Article information

DOI: https://doi.org/10.1039/D0GC02667K
Article type: Communication
Submitted: 03 Aug 2020
Accepted: 24 Sep 2020
First published: 24 Sep 2020

Download Citation

Green Chem., 2020,22, 7328-7332

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Rh(I)-Catalyzed regioselective arylcarboxylation of acrylamides with arylboronic acids and CO₂

L. Cai, L. Fu, C. Zhou, Y. Gao, S. Li and G. Li, Green Chem., 2020, 22, 7328 DOI: 10.1039/D0GC02667K

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