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Issue 21, 2020
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Environmentally sustainable production and application of acyl phosphates

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Abstract

A versatile and environmentally friendly synthetic method for the formation of acyl phosphates is reported. By employing electrochemical oxidative dehydrogenative coupling, this transformation features a broad range of substrates, as well as metal-free, oxidant-free and mild conditions. One-pot synthesis of amides from acyl phosphates with amines was accomplished with high efficiency and regioselectivity, without using any additional catalysts and additives, within 2 hours under room temperature. The mechanism is proposed according to the control experiments.

Graphical abstract: Environmentally sustainable production and application of acyl phosphates

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Article information


Submitted
13 Jul 2020
Accepted
05 Oct 2020
First published
05 Oct 2020

Green Chem., 2020,22, 7343-7347
Article type
Communication

Environmentally sustainable production and application of acyl phosphates

S. Guo, S. Li, W. Yan, Z. Liang, Z. Fu and H. Cai, Green Chem., 2020, 22, 7343
DOI: 10.1039/D0GC02370A

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