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Issue 19, 2020
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Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

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Abstract

Herein, novel photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O is reported. The protocol was compatible with a variety of functionalities, including halogen, alkoxy, cyano, sulfonyl, trimethylsilyl, trifluoromethoxy, alkyl, hydroxyl, free acid, amide, and heteroaromatic rings. A wide range of deuterated products were obtained in good yields with a high level of deuteration. This method provides a green and practical pathway to synthesize deuterium labelled compounds under mild conditions.

Graphical abstract: Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

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Supplementary files

Article information


Submitted
15 May 2020
Accepted
01 Jul 2020
First published
10 Jul 2020

Green Chem., 2020,22, 6323-6327
Article type
Communication

Photoinduced catalyst-free deborylation–deuteration of arylboronic acids with D2O

Y. Lang, X. Peng, C. Li and H. Zeng, Green Chem., 2020, 22, 6323
DOI: 10.1039/D0GC01649G

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