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Calcium carbide as a dehydrating agent for the synthesis of carbamates, glycerol carbonate, and cyclic carbonates from carbon dioxide

Abstract

Carbon dioxide (CO2) is a nontoxic and inexpensive C1 building block, which can be used for the synthesis of valuable chemicals such as aromatic carbamates from anilines and methanol (MeOH), glycerol carbonate from glycerol, and cyclic carbonates from diols. However, these reactions generate water as byproduct and suffer from thermodynamic limits, which lead to low yields. Calcium carbide (CaC2) is a renewable chemical, which can be recycled from calcium that is abundant in the Earth’s crust. Furthermore, CaC2 rapidly reacts with water. In this work, we used CaC2 as dehydrating agent for the direct synthesis of carbamate (including polyurethane precursors) from amine, CO2, and MeOH. All reagents were commercially available. In addition, CaC2 was employed for the synthesis of glycerol carbonate from glycerol and CO2 with a zinc catalyst and N-donor ligand. A similar protocol was applied to synthesize cyclic carbonates from diols and CO2.

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Supplementary files

Article information


Submitted
22 Apr 2020
Accepted
15 May 2020
First published
18 May 2020

Green Chem., 2020, Accepted Manuscript
Article type
Paper

Calcium carbide as a dehydrating agent for the synthesis of carbamates, glycerol carbonate, and cyclic carbonates from carbon dioxide

Q. Zhang, H. Yuan, X. Lin, N. Fukaya, T. Fujitani, K. Sato and J. Choi, Green Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0GC01402H

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