Jump to main content
Jump to site search

Issue 15, 2020
Previous Article Next Article

Introducing the reversible chemistry of CO2 with diols mediated by organic superbases into polycarbonate synthesis

Author affiliations

Abstract

The reversible reaction of CO2 with alcohols in the presence of organic bases was successfully developed to be a toolbox for capturing CO2 into polymerizable α,ω-diene functionalized carbonate monomers with high structural diversity. These are applicable for thiol–ene click and ADMET polymerization to produce new libraries of poly(thioether carbonates) and unsaturated aromatic–aliphatic polycarbonates with high molecular weights and satisfactory thermal properties.

Graphical abstract: Introducing the reversible chemistry of CO2 with diols mediated by organic superbases into polycarbonate synthesis

Back to tab navigation

Supplementary files

Article information


Submitted
04 Apr 2020
Accepted
12 May 2020
First published
13 May 2020

Green Chem., 2020,22, 4871-4877
Article type
Communication

Introducing the reversible chemistry of CO2 with diols mediated by organic superbases into polycarbonate synthesis

Y. Chai, Q. Chen, C. Huang, Q. Zheng, M. North and H. Xie, Green Chem., 2020, 22, 4871
DOI: 10.1039/D0GC01197E

Social activity

Search articles by author

Spotlight

Advertisements