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Developing benign syntheses using ion pairs via solvent-free mechanochemistry

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Abstract

Solvent-free mechanochemical conditions have been developed to investigate the significance of ion pairing and the use of weak bases for driving forward nucleophilic substitution reactions. This approach takes advantage of the lack of solvent shells to incorporate weaker and safer bases to drive reactions to completion through specific ion pairing pathways. The most efficient reactions contained larger and more polarizable cation and anion pairs.

Graphical abstract: Developing benign syntheses using ion pairs via solvent-free mechanochemistry

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Article information


Submitted
29 Mar 2020
Accepted
11 May 2020
First published
11 May 2020

Green Chem., 2020, Advance Article
Article type
Paper

Developing benign syntheses using ion pairs via solvent-free mechanochemistry

L. N. Ortiz-Trankina, J. Crain, C. Williams and J. Mack, Green Chem., 2020, Advance Article , DOI: 10.1039/D0GC01116A

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