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Catalytic deoxygenation of bio-based 3-hydroxydecanoic acid to secondary alcohols and alkanes

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Abstract

This work comprises the selective deoxygenation of bio-derivable 3-hydroxydecanoic acid to either linear alkanes or secondary alcohols in aqueous phase and H2-atmosphere over supported metal catalysts. Among the screened catalysts, Ru-based systems were identified to be most active. By tailoring the catalyst, the product selectivity could be directed to either secondary alcohols or linear alkanes. In the absence of a Brønsted acidic additive, 2-nonanol and 3-decanol were accessible with a yield of 79% and 6% respectively, both of which can be used in food and perfume industries as flavoring agents and fragrances. To produce alkanes, we successfully synthesized a bifunctional Ru/HZSM-5 catalyst. The acidic zeolite support facilitated the dehydration of the intermediary formed alcohols to alkenes, while the following hydrogenation occurred at the Ru centers. Thus, full 3-hydroxydecanoic acid deoxygenation to nonane and decane, which are both well-established as diesel and jet fuels, was achieved with up to 72% and 12% yield, respectively.

Graphical abstract: Catalytic deoxygenation of bio-based 3-hydroxydecanoic acid to secondary alcohols and alkanes

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Supplementary files

Article information


Submitted
26 Feb 2020
Accepted
06 May 2020
First published
13 May 2020

Green Chem., 2020, Advance Article
Article type
Paper

Catalytic deoxygenation of bio-based 3-hydroxydecanoic acid to secondary alcohols and alkanes

J. B. Mensah, A. H. Hergesell, S. Brosch, C. Golchert, J. Artz and R. Palkovits, Green Chem., 2020, Advance Article , DOI: 10.1039/D0GC00691B

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