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Manganese Catalyzed Selective Hydrogenation of Cyclic Imides to Diols and Amines

Abstract

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

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Article information


Submitted
16 Feb 2020
Accepted
17 Mar 2020
First published
19 Mar 2020

Green Chem., 2020, Accepted Manuscript
Article type
Communication

Manganese Catalyzed Selective Hydrogenation of Cyclic Imides to Diols and Amines

U. K. Das, T. Janes, A. Kumar and D. Milstein, Green Chem., 2020, Accepted Manuscript , DOI: 10.1039/D0GC00570C

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