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Issue 10, 2020
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Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

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Abstract

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

Graphical abstract: Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

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Article information


Submitted
16 Feb 2020
Accepted
17 Mar 2020
First published
19 Mar 2020

Green Chem., 2020,22, 3079-3082
Article type
Communication

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

U. K. Das, T. Janes, A. Kumar and D. Milstein, Green Chem., 2020, 22, 3079
DOI: 10.1039/D0GC00570C

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