Issue 10, 2020

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Abstract

Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.

Graphical abstract: Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

Supplementary files

Article information

Article type
Communication
Submitted
16 Feb 2020
Accepted
17 Mar 2020
First published
19 Mar 2020

Green Chem., 2020,22, 3079-3082

Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines

U. K. Das, T. Janes, A. Kumar and D. Milstein, Green Chem., 2020, 22, 3079 DOI: 10.1039/D0GC00570C

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