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Continuous flow Suzuki–Miyaura couplings in water under micellar conditions in a CSTR cascade catalyzed by Fe/ppm Pd nanoparticles

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Abstract

The first demonstration of aqueous surfactant-enabled Suzuki–Miyaura couplings run under flow conditions is described. In addition, use of an even more challenging heterogeneous nanoparticle catalyst, containing only 800 ppm of Pd (i.e., 0.08 mol%) in the form of Fe/ppm Pd nanoparticles, is sufficient using a continuous stirred-tank reactor (CSTR).

Graphical abstract: Continuous flow Suzuki–Miyaura couplings in water under micellar conditions in a CSTR cascade catalyzed by Fe/ppm Pd nanoparticles

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Article information


Submitted
30 Jan 2020
Accepted
11 May 2020
First published
14 May 2020

Green Chem., 2020, Advance Article
Article type
Communication

Continuous flow Suzuki–Miyaura couplings in water under micellar conditions in a CSTR cascade catalyzed by Fe/ppm Pd nanoparticles

A. B. Wood, K. Y. Nandiwale, Y. Mo, B. Jin, A. Pomberger, V. L. Schultz, F. Gallou, K. F. Jensen and B. H. Lipshutz, Green Chem., 2020, Advance Article , DOI: 10.1039/D0GC00378F

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