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A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

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Abstract

Porous crystalline materials, such as porous organic cages (POCs) and covalent organic frameworks (COFs), are important for a wide range of applications such as gas storage/separation, sensing and catalysis. A conventional synthetic approach for imine-based POCs and COFs usually involves the use of organic solvents/acid catalysts (such as AcOH or TFA). However, synthesizing and growing POC crystals and COF crystallites with enhanced crystallinity is not an easy-to-perform process, in which many reaction parameters need to be screened. To overcome these problems, we have proposed herein a facile and green synthetic strategy by adopting H2O/organic solvents/MOH (M = Na, K, and Cs) as reaction media to produce a series of phenol-based POCs and COFs. X-ray crystallography and molecular simulations have been used to confirm their structures in addition to NMR, mass and FT-IR spectra, and gas sorption experiments reveal their porosity and sorption properties. This new approach provides not only an efficient and alternative route to synthesize highly crystalline POCs and even COFs, but also insight into the crystallization process of these two kinds of porous materials, especially in the hydrous media.

Graphical abstract: A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

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Article information


Submitted
25 Nov 2019
Accepted
10 Mar 2020
First published
13 Mar 2020

Green Chem., 2020, Advance Article
Article type
Paper

A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

L. Zhang, R. Liang, C. Hang, H. Wang, L. Sun, L. Xu, D. Liu, Z. Zhang, X. Zhang, F. Chang, S. Zhao and W. Huang, Green Chem., 2020, Advance Article , DOI: 10.1039/C9GC04033A

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