Issue 6, 2020
From the journal:

Green Chemistry

Synthesis of α-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent†

Biping Xu, ORCID logo ab   Yaping Shang, ORCID logo *a   Xiaoming Jie,a   Xiaofeng Zhang, ORCID logo a   Jian Kan,a   Subhash Laxman Yedagea  and  Weiping Su ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: wpsu@fjirsm.ac.cn, shangyaping@fjirsm.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

A convenient and straightforward transformation of cyclic ketones with anilines at room temperature has been developed using oxoammonium salt TEMPO+PF6− as an oxidant. This method enabled the synthesis of a broad range of α-enaminones. The 18O-labeling experiment demonstrated that oxoammonium salt served as the oxygen transfer reagent.

Graphical abstract: Synthesis of α-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9GC03845K
Article type
Communication
Submitted
08 Nov 2019
Accepted
02 Jan 2020
First published
07 Jan 2020

Green Chem., 2020,22, 1827-1831

Permissions

Request permissions

Synthesis of α-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent

B. Xu, Y. Shang, X. Jie, X. Zhang, J. Kan, S. L. Yedage and W. Su, Green Chem., 2020, 22, 1827 DOI: 10.1039/C9GC03845K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements