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Solid Electrolyte Interphase (SEI) in Potassium Ion Batteries


Potassium-ion batteries (PIBs) have attracted considerable interest as large-scale energy storage candidates owing to a naturally abundant potassium resource and low cost. Since the birth of PIBs, the solid electrolyte interphase (SEI) has been a critical concern, which plays a vital role in the Coulombic efficiency, cycling stability and even safety of batteries. However, the SEI of PIBs mains poorly understood. In this review, we begin with a discussion regarding the differences in the chemical composition and structure of K-ion SEI versus the much better-known Li-ion and Na-ion SEI. Unanswered scientific questions on nature of K-ion SEI are clearly identified. We review findings used to understand the formation mechanism of SEI on graphite, the existence of SEI in ether-based electrolyte is openly debated. The current understanding of SEI on different types of anodes is comprehensively summarized and discussed, with an emphasis on how the enhanced stability of SEI fundamentally affects the efficiency and reversibility of electrochemical reactions. Finally, we detail the major challenges of anodes and discuss the emerging research directions for further development of PIBs.

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Article information

22 May 2020
23 Sep 2020
First published
23 Sep 2020

Energy Environ. Sci., 2020, Accepted Manuscript
Article type
Review Article

Solid Electrolyte Interphase (SEI) in Potassium Ion Batteries

H. Wang, D. Zhai and F. Kang, Energy Environ. Sci., 2020, Accepted Manuscript , DOI: 10.1039/D0EE01638A

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