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The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; nitrite reduction mediated by a V(iii) complex

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Abstract

A V(III) complex bearing a tris(thiolato)phoshine derivative mediates the reduction of nitrite without the assistance of external protons or oxophilic substrates. The metal site plays dual roles for nitrite binding and deoxygenation. The reaction is monitored by spectroscopy combined with isotopic labeling experiments. The formed product, a {VNO}4 species, is isolated and characterized.

Graphical abstract: The dual roles of a V(iii) centre for substrate binding and oxygen atom abstraction; nitrite reduction mediated by a V(iii) complex

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Article information


Submitted
19 Sep 2020
Accepted
23 Sep 2020
First published
25 Sep 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

The dual roles of a V(III) centre for substrate binding and oxygen atom abstraction; nitrite reduction mediated by a V(III) complex

H. Pan, Z. Wu, C. Kuo, H. Ou, G. Lee and H. Hsu, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT03274C

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