Jump to main content
Jump to site search


2-Arylbenzo[b]arsoles: an experimental and computational study on the relationship between structural and photophysical properties

Author affiliations

Abstract

Benzo[b]arsole derivatives, being arsenic analogues of indole, were synthesized by utilizing a safely prepared arsenic precursor. The structural and photophysical properties of the obtained 2-arylbenzo[b]arsoles were experimentally and computationally studied in comparison with those of 1,2,5-triarylarsoles and 9-phenylarsafluorene. It was found that the emission color and/or quantum yield were significantly affected by substituents on the luminescent center and metal-coordination to the arsenic atom. This is the first study on the structure–property relationship of benzo[b]arsole derivatives.

Graphical abstract: 2-Arylbenzo[b]arsoles: an experimental and computational study on the relationship between structural and photophysical properties

Back to tab navigation

Supplementary files

Article information


Submitted
30 Jul 2020
Accepted
01 Sep 2020
First published
03 Sep 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

2-Arylbenzo[b]arsoles: an experimental and computational study on the relationship between structural and photophysical properties

K. Ishijima, S. Tanaka, H. Imoto and K. Naka, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT02669G

Social activity

Search articles by author

Spotlight

Advertisements