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Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

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Abstract

Late-stage direct functionalization of the C–H bond is synthetically desirable. Metalloenzymes having metal-oxo active sites are well known to selectively catalyze hydroxylation and halogenation reactions with high efficiency. This review highlights the recent developments in the field of direct C–H halogenation and pseudohalogenation reactions catalyzed by the functional models of metalloenzymes.

Graphical abstract: Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

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Article information


Submitted
18 Jul 2020
Accepted
18 Sep 2020
First published
21 Sep 2020

Dalton Trans., 2020, Advance Article
Article type
Perspective

Direct C–H bond halogenation and pseudohalogenation of hydrocarbons mediated by high-valent 3d metal-oxo species

N. Kannan, A. R. Patil and A. Sinha, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT02533J

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