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Using sodium acetate for the synthesis of [Au(NHC)X] complexes

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Abstract

The role of sodium acetate in the synthesis of [Au(NHC)Cl] complexes was examined. The use of this base was also investigated for the activation of C–H and S–H bonds by experimental and computational methods. The synthetic use of NaOAc to assemble these complexes is applicable to a wide range of NHCs and proceeds under air, under mild conditions and using technical grade green solvents.

Graphical abstract: Using sodium acetate for the synthesis of [Au(NHC)X] complexes

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Supplementary files

Article information


Submitted
24 Jun 2020
Accepted
25 Jun 2020
First published
26 Jun 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

Using sodium acetate for the synthesis of [Au(NHC)X] complexes

T. Scattolin, N. V. Tzouras, L. Falivene, L. Cavallo and S. P. Nolan, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT02240C

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