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Issue 33, 2020
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X-ray pair distribution function analysis and electrical and electrochemical properties of cerium doped Li5La3Nb2O12 garnet solid-state electrolyte

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Abstract

Garnet solid state electrolytes have been considered as potential candidates to enable next generation all solid state batteries (ASSBs). To facilitate the practical application of ASSBs, a high room temperature ionic conductivity and a low interfacial resistance between solid state electrolyte and electrodes are essential. In this work, we report a study of cerium doped Li5La3Nb2O12 through X-ray pair distribution function analysis, impedance spectroscopy and electrochemical testing. The successful cerium incorporation was confirmed by both X-ray diffraction refinement and X-ray pair distribution function analysis, showing the formation of an extensive solid solution. The local bond distances for Ce and Nb on the octahedral site were determined using X-ray pair distribution function analysis, illustrating the longer bond distances around Ce. This Ce doping strategy was shown to give a significant enhancement in conductivity (1.4 × 10−4 S cm−1 for Li5.75La3Nb1.25Ce0.75O12, which represents one of the highest conductivities for a garnet with less than 6 Li) as well as a dramatically decreased interfacial resistance (488 Ω cm2 for Li5.75La3Nb1.25Ce0.75O12). In order to demonstrate the potential of this doped system for use in ASSBs, the long term cycling of a Li//garnet//Li symmetric cell over 380 h has been demonstrated.

Graphical abstract: X-ray pair distribution function analysis and electrical and electrochemical properties of cerium doped Li5La3Nb2O12 garnet solid-state electrolyte

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Submitted
14 Jun 2020
Accepted
10 Aug 2020
First published
10 Aug 2020

This article is Open Access

Dalton Trans., 2020,49, 11727-11735
Article type
Paper

X-ray pair distribution function analysis and electrical and electrochemical properties of cerium doped Li5La3Nb2O12 garnet solid-state electrolyte

B. Dong, M. P. Stockham, P. A. Chater and P. R. Slater, Dalton Trans., 2020, 49, 11727
DOI: 10.1039/D0DT02112A

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