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Cooperative strategies for CO homologation

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Abstract

Recent approaches in which at least two metal or main-group centres are involved in the homologation of CO are reviewed. We have characterised the strategies into three broad areas: (i) the reductive homologation of atmospheric CO at a metal or main group centre (ii) the reductive homologation of metal–carbonyl CO units and (iii) reductive homologation of CO with M–M, B–Li, Si[double bond, length as m-dash]Si, and B[triple bond, length as m-dash]B bonds.

Graphical abstract: Cooperative strategies for CO homologation

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Article information


Submitted
29 Apr 2020
Accepted
06 Jun 2020
First published
08 Jun 2020

This article is Open Access

Dalton Trans., 2020, Advance Article
Article type
Frontier

Cooperative strategies for CO homologation

R. Y. Kong and M. R. Crimmin, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT01564D

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