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Issue 23, 2020

Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

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Abstract

A combined computational and experimental approach demonstrates the accelerating role of deaggregation agents, especially HMPA, in the Li-catalysed hydrosilylation of acetophenone in THF solution under very mild conditions.

Graphical abstract: Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

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Article information


Submitted
27 Apr 2020
Accepted
26 May 2020
First published
03 Jun 2020

Dalton Trans., 2020,49, 7932-7937
Article type
Paper

Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds

C. Ruiz, Á. Raya-Barón, M. A. Ortuño and I. Fernández, Dalton Trans., 2020, 49, 7932 DOI: 10.1039/D0DT01540G

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