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Probing the electronic boundaries between trigonal and tetrahedral coordination at beryllium

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Abstract

NEt3 adducts to BeCl2, BeBr2 and BeI2 were synthesized and characterised via NMR and IR spectroscopy as well as X-ray diffractometry. Depending on the halide and the state of matter these are either mono- or dinuclear. Population analyses were performed to determine the influence of the metal's partial charge on the coordination geometry. Additionally, the reactivity of these compounds towards C–Cl- and O–H-bonds was studied.

Graphical abstract: Probing the electronic boundaries between trigonal and tetrahedral coordination at beryllium

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Article information


Submitted
20 Apr 2020
Accepted
23 Apr 2020
First published
23 Apr 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

Probing the electronic boundaries between trigonal and tetrahedral coordination at beryllium

M. R. Buchner, M. Müller and N. Spang, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT01442G

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