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Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

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Abstract

We report the first application of a rigid P2N3 pincer ligand in p-block chemistry by preparing its bismuth complex. We also report the first example of bismuth complexes featuring a flexible PNP pincer ligand, which shows phase-dependent structural dynamics. Highly electrophilic, albeit thermally unstable, Bi(III) complexes of the PNP ligand were also prepared.

Graphical abstract: Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

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Article information


Submitted
18 Apr 2020
Accepted
11 May 2020
First published
20 May 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Squeezing Bi: PNP and P2N3 pincer complexes of bismuth

M. B. Kindervater, T. Hynes, K. M. Marczenko and S. S. Chitnis, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT01413C

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