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Issue 21, 2020
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A ferrocene-templated Pd-bearing molecular reactor

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Abstract

High-yield, chromatography-free syntheses of a ferrocene-templated molecular cage and its Pd-bearing derivative are presented. The formation of a symmetric cage-type structure was confirmed by single-crystal X-ray diffraction analysis. The Pd-bearing cage was used as an innovative catalyst for the efficient synthesis of 1,1′-biphenyls under mild conditions. The presented catalyst is reusable and 1,1′-biphenyls can be obtained efficiently in a gram scale process.

Graphical abstract: A ferrocene-templated Pd-bearing molecular reactor

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Article information


Submitted
14 Apr 2020
Accepted
12 May 2020
First published
12 May 2020

Dalton Trans., 2020,49, 6974-6979
Article type
Communication

A ferrocene-templated Pd-bearing molecular reactor

A. Kasprzak and P. A. Guńka, Dalton Trans., 2020, 49, 6974
DOI: 10.1039/D0DT01366H

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