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Issue 20, 2020
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A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior

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Abstract

New trinuclear gold(I) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2]+ isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag+ cation.

Graphical abstract: A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior

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Article information


Submitted
03 Apr 2020
Accepted
17 Apr 2020
First published
17 Apr 2020

Dalton Trans., 2020,49, 6561-6565
Article type
Communication

A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

J. Ruiz, D. Sol, M. A. Mateo, M. Vivanco and R. Badía-Laiño, Dalton Trans., 2020, 49, 6561
DOI: 10.1039/D0DT01246G

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