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Metal–metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Abstract

An N-heterocyclic carbene triplatinum complex with two triply bridging sulfide ligands reacts with a silver(I) salt and affords a heptanuclear complex. X-ray crystallographic analysis revealed that a silver(I) ion connects two triplatinum complexes with one of the three Pt–Pt bonds of each triplatinum unit.

Graphical abstract: Metal–metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

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Article information


Submitted
02 Apr 2020
Accepted
27 Apr 2020
First published
28 Apr 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Metal–metal bond formation of triplatinum cores with a silver(I) ion affording a heptanuclear cluster bearing four Pt–Ag bonds

N. Yabune, H. Nakajima and T. Nishioka, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT01227K

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