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Structures and paramagnetism of five heterometallic pentanuclear metal strings containing as many as four different metals: NiPtCo2Pd(tpda)4Cl2

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Abstract

Five heterometallic pentanuclear metal strings were prepared by stepwise synthesis from two to three and four kinds of metals aligned in one chain. In particular, NiPtCo2Pd(tpda)4Cl2 (5) possesses four different metals, and the SQUID measurement shows that Ni2+ is the only magnetically active center. Besides, the shortest Co(II)–Co(II) single bond (2.105(9) Å), so far, is reported.

Graphical abstract: Structures and paramagnetism of five heterometallic pentanuclear metal strings containing as many as four different metals: NiPtCo2Pd(tpda)4Cl2

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Article information


Submitted
23 Mar 2020
Accepted
20 Apr 2020
First published
22 Apr 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Structures and paramagnetism of five heterometallic pentanuclear metal strings containing as many as four different metals: NiPtCo2Pd(tpda)4Cl2

M. Cheng, R. Huang, Y. Liu, M. Chiang, G. Lee, Y. Song, T. Lin and S. Peng, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT01088J

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