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Issue 26, 2020
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Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

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Abstract

For the first time, a new square Ca4O SBU is introduced into a 3D Ca-MOF, ([MeNH2]2[Ca4O(MTB)2(EtOH)4])·(solvent)n (1), to generate a (4,8)-connected flu-topology structure. Compound 1 exhibits selective adsorption of C3 and C2 hydrocarbons and CO2 over CH4 with especially high IAST selectivities for C3 hydrocarbons over CH4 (at 15/85 and 50/50 ratio) at 298K and 1 bar.

Graphical abstract: Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

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Supplementary files

Article information


Submitted
13 Mar 2020
Accepted
02 Jun 2020
First published
03 Jun 2020

Dalton Trans., 2020,49, 8836-8840
Article type
Communication

Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

F. Hu, Z. Di, M. Wu and J. Li, Dalton Trans., 2020, 49, 8836
DOI: 10.1039/D0DT00943A

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