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Synthesis and study of Fe → Pd interactions in unsymmetric Pd(ii) complexes with phosphinoferrocene guanidine ligands

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Abstract

Readily available phosphinoferrocene guanidines coordinate Pd(II) as P,N-chelating or κ3P,N,Fe-bound ligands. As the latter, they give rise to the first donor-asymmetric complexes featuring Fe–Pd dative bonds, which were studied using direct (spectroscopic and electrochemical) methods and theoretical (DFT) approaches.

Graphical abstract: Synthesis and study of Fe → Pd interactions in unsymmetric Pd(ii) complexes with phosphinoferrocene guanidine ligands

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Article information


Submitted
04 Mar 2020
Accepted
16 Mar 2020
First published
16 Mar 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Synthesis and study of Fe → Pd interactions in unsymmetric Pd(II) complexes with phosphinoferrocene guanidine ligands

O. Bárta, R. Gyepes, I. Císařová, A. Alemayehu and P. Štěpnička, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT00812E

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