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Issue 10, 2020
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First demonstration of the π–f orbital interaction depending on the coordination geometry in Eu(iii) luminophores

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Abstract

Herein, the π–f orbital interaction depending on the coordination geometry in the Eu(III) complex is demonstrated. Thermal analysis and computational calculations showed the phase transition of the Eu(III) complex based on the change in the coordination geometry. A red-shifted LMCT band and radiative rate changes associated with the phase transition were found in the Eu(III) complex.

Graphical abstract: First demonstration of the π–f orbital interaction depending on the coordination geometry in Eu(iii) luminophores

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Submitted
13 Feb 2020
Accepted
20 Feb 2020
First published
02 Mar 2020

Dalton Trans., 2020,49, 3098-3101
Article type
Communication

First demonstration of the π–f orbital interaction depending on the coordination geometry in Eu(III) luminophores

Y. Kitagawa, M. Kumagai, P. P. Ferreira da Rosa, K. Fushimi and Y. Hasegawa, Dalton Trans., 2020, 49, 3098
DOI: 10.1039/D0DT00528B

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