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Issue 14, 2020
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Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

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Abstract

Two FeII8L12 cubic metal–organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I2 and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.

Graphical abstract: Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

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Article information


Submitted
31 Jan 2020
Accepted
11 Mar 2020
First published
12 Mar 2020

Dalton Trans., 2020,49, 4220-4224
Article type
Communication

Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

H. Lu, W. Han, X. Yan, Y. Xu, H. Zhang, T. Li, Y. Gong, Q. Hu and Z. Gu, Dalton Trans., 2020, 49, 4220
DOI: 10.1039/D0DT00353K

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