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Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

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Abstract

Two FeII8L12 cubic metal–organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I2 and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.

Graphical abstract: Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

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Article information


Submitted
31 Jan 2020
Accepted
11 Mar 2020
First published
12 Mar 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

H. Lu, W. Han, X. Yan, Y. Xu, H. Zhang, T. Li, Y. Gong, Q. Hu and Z. Gu, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT00353K

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