Supramolecular assemblies based on Fe8L12 cubic metal–organic cages: synergistic adsorption and spin-crossover properties

Hui-Shu Lu; Wang-Kang Han; Xiaodong Yan; Ya-Xin Xu; Hai-Xia Zhang; Tao Li; Yu Gong; Qing-Tao Hu; Zhi-Guo Gu

doi:10.1039/D0DT00353K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Supramolecular assemblies based on Fe₈L₁₂ cubic metal–organic cages: synergistic adsorption and spin-crossover properties†

Hui-Shu Lu,‡^a Wang-Kang Han,‡^a Xiaodong Yan,

^a Ya-Xin Xu,^a Hai-Xia Zhang,^a Tao Li,^a Yu Gong,^a Qing-Tao Hu^a and Zhi-Guo Gu

*^ab

Author affiliations

* Corresponding authors

^a The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P.R. China
E-mail: zhiguogu@jiangnan.edu.cn

^b International Joint Research Center for Photo responsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P.R. China

Abstract

Two Fe^II₈L₁₂ cubic metal–organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I₂ and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D0DT00353K
Article type: Communication
Submitted: 31 Jan 2020
Accepted: 11 Mar 2020
First published: 12 Mar 2020

Download Citation

Dalton Trans., 2020,49, 4220-4224

Permissions

Request permissions

Supramolecular assemblies based on Fe₈L₁₂ cubic metal–organic cages: synergistic adsorption and spin-crossover properties

H. Lu, W. Han, X. Yan, Y. Xu, H. Zhang, T. Li, Y. Gong, Q. Hu and Z. Gu, Dalton Trans., 2020, 49, 4220 DOI: 10.1039/D0DT00353K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions