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Hexahydroxytriphenylene for the synthesis of group 13 MOFs – a new inorganic building unit in a β-cristobalite type structure

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Abstract

Two new, microporous MOFs of framework composition ((CH3)2NH2)2[M3O(HHTP)(HHTP˙)], M = Al3+, Ga3+, H6HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene, are described. Electron diffraction combined with molecular simulations show that these compounds crystallize in the β-cristobalite structure, containing a new type of trinuclear inorganic building unit for MOFs and radical anions.

Graphical abstract: Hexahydroxytriphenylene for the synthesis of group 13 MOFs – a new inorganic building unit in a β-cristobalite type structure

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Article information


Submitted
21 Jan 2020
Accepted
07 Feb 2020
First published
07 Feb 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Hexahydroxytriphenylene for the synthesis of group 13 MOFs – a new inorganic building unit in a β-cristobalite type structure

S. Leubner, V. E. G. Bengtsson, A. K. Inge, M. Wahiduzzaman, F. Steinke, A. Jaworski, H. Xu, S. Halis, P. Rönfeldt, H. Reinsch, G. Maurin, X. Zou and N. Stock, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT00235F

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