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Issue 13, 2020
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Synergistic ligand effect for the construction of titanium–oxo clusters with planar chirality and high solution stability

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Abstract

A synergistic effect between dimethylglyoxime (to stabilize the Ti–O ribbon) and nonlinear dicarboxylate ligands (to bend the Ti–O ribbon) has been developed to form a series of planar chiral titanium–oxo clusters with high solution stability. The charality of the obtained clusters has been studied by X-ray structural and CD spectroscopy analysis.

Graphical abstract: Synergistic ligand effect for the construction of titanium–oxo clusters with planar chirality and high solution stability

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Supplementary files

Article information


Submitted
17 Jan 2020
Accepted
24 Feb 2020
First published
25 Feb 2020

Dalton Trans., 2020,49, 4030-4033
Article type
Communication

Synergistic ligand effect for the construction of titanium–oxo clusters with planar chirality and high solution stability

Q. Ding, G. Xu, J. Zhang and L. Zhang, Dalton Trans., 2020, 49, 4030
DOI: 10.1039/D0DT00197J

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