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New Cu(I) halide complexes showing TADF combined with room temperature phosphorescence: the balance tuned by halogens

Abstract

A series of Cu(I) halide complexes derived from tris(2-pyridyl)phosphine (Py3P), [Cu2(Py3P)2X2] (X = Cl, Br, I), has been synthesized by straightforward reaction in solution or through a mechanochemical route. At room temperature, the solid complexes exhibit bright dual-mode photoluminescence (λmax = 520–550 nm, τ = 14.5–20.0 µs, ΦPL ≈ 53%), expressed by thermally activated delayed fluorescence (TADF) combined with phosphorescence (PH), originating form 1(M+X)LCT and 3(M+X)LCT excited states, respectively. Remarkably, the balance of these radiative processes at 300 K is regulated by halogen atom nature, switching from TADF-assistant phosphorescence to PH-admixed TADF. The emission of [Cu2(Py3P)2Cl2] at 300 K is largely contributed by PH (73%) admixed with the TADF fraction (27%), [Cu2(Py3P)2Br2] also emits mainly PH (65%) admixed with the bigger TADF fraction (35%). Meanwhile, for [Cu2(Py3P)2I2], TADF channel becomes dominating (61%), and PH contribution drops to 39%. The photophysical study corroborated by (TD)DFT computations has revealed that this effect arises mainly from a narrowing of the ΔE(S1−T1) gap of the [Cu2(Py3P)2X2] complexes in the order Cl (1500 cm−1) > Br (1250 cm−1) > I (1000 cm−1) that facilitates TADF pathway and suppresses PH in the same order.

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Supplementary files

Article information


Submitted
17 Jan 2020
Accepted
06 Feb 2020
First published
07 Feb 2020

Dalton Trans., 2020, Accepted Manuscript
Article type
Paper

New Cu(I) halide complexes showing TADF combined with room temperature phosphorescence: the balance tuned by halogens

A. Baranov, A. S. Berezin, D. G. Samsonenko, A. Mazur, P. Tolstoy, V. F. Plyusnin, I. Kolesnikov and A. Artem'ev, Dalton Trans., 2020, Accepted Manuscript , DOI: 10.1039/D0DT00192A

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