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Gd(NO3)(Se2O5).3H2O: A nitrate-selenite nonlinear optical material with a short ultraviolet cutoff edge

Abstract

The first example of rare-earth metal nitrate-selenite nonlinear optical (NLO) crystal, Gd(NO3)(Se2O5).3H2O (1), was synthesized by hydrothermal reaction. This compound crystallizes in the noncentrosymmetric space group P212121, and its structure features two-dimensional (2D) [Gd(NO3)(Se2O5)]∞ layers, then extending to a pseudo-3D framework linked by hydrogen bonds. 1 exhibits a phase-matchable SHG efficiency of about 0.2 times that of KH2PO4 (KDP) and a large laser damage threshold of 236.26 MW/cm2. UV-Vis-NIR diffuse reflectance spectroscopy study shows that the UV cutoff edge of 1 is 224 nm, which is the shortest value observed among selenite-based NLO materials. The birefringence of 1 is 0.109@1064 nm based on density functional theory calculations. These optical properties render 1 a potential UV NLO material. Theoretical studies using density functional theory have been implemented to further understand the relationship between its optical properties and band structures.

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Article information


Submitted
11 Jan 2020
Accepted
12 Feb 2020
First published
12 Feb 2020

Dalton Trans., 2020, Accepted Manuscript
Article type
Paper

Gd(NO3)(Se2O5).3H2O: A nitrate-selenite nonlinear optical material with a short ultraviolet cutoff edge

C. Wu, L. Li, L. Lin, Z. Huang, M. G. Humphrey and C. Zhang, Dalton Trans., 2020, Accepted Manuscript , DOI: 10.1039/D0DT00116C

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