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Issue 13, 2020
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Single-molecule magnet behavior in luminescent carbazolyl Dy(iii) octahedral complexes with a quasi linear N–Dy–N angle

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Abstract

We report the synthesis, photoluminescence and magnetic properties of two octahedral dysprosium complexes [DyR2(py)4][BPh4]·2py (1) and [DyR2(THF)4][BPh4] (2) (R = carbazolyl, py = pyridine, THF = tetrahydrofuran) exhibiting a quasi linear N–Dy–N angle in the axial direction, suitable for providing a coordination environment allowing the zero-field slow relaxation of magnetization.

Graphical abstract: Single-molecule magnet behavior in luminescent carbazolyl Dy(iii) octahedral complexes with a quasi linear N−–Dy–N− angle

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Article information


Submitted
08 Jan 2020
Accepted
29 Feb 2020
First published
02 Mar 2020

Dalton Trans., 2020,49, 4039-4043
Article type
Communication

Single-molecule magnet behavior in luminescent carbazolyl Dy(III) octahedral complexes with a quasi linear N–Dy–N angle

J. Long, A. N. Selikhov, E. Mamontova, K. A. Lyssenko, Y. Guari, J. Larionova and A. A. Trifonov, Dalton Trans., 2020, 49, 4039
DOI: 10.1039/D0DT00072H

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