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[Bmmim]6[In10Se16Cl4]·(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation

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Abstract

An indium selenide [Bmmim]6[In10Se16Cl4]·(MIm)2 (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen evolution activity at least six times that of the pristine in the solid state due to the exposure of more active sites.

Graphical abstract: [Bmmim]6[In10Se16Cl4]·(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation

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Article information


Submitted
02 Jan 2020
Accepted
11 Mar 2020
First published
11 Mar 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

[Bmmim]6[In10Se16Cl4]·(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation

Y. Wang, Q. Hu, J. Jin, J. Li, J. Li and X. Huang, Dalton Trans., 2020, Advance Article , DOI: 10.1039/D0DT00013B

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